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Q.

The standard free energy change ΔG° for 50 % dissociation of N2O4 into NO2 at 27°C and 1 atm pressure is -x J mol-1. The value of x is _________.(Nearest Integer)
[Given : R=8.31 J K-1 mol-1,log1.33=0.1239 ln10=2.3]

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answer is 710.

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Detailed Solution

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              N2O4          2NO2             1 mol                    0  (10.5)mol      0.5×2mol            0.5 mol               1 mol  kP=11.5×120.51.5×1=10.75=10075 =1.33 ΔG0=RTℓnkP ΔG0=RT(2.3) log kP =8.31×300×ln(1.33)=710.45J/mol =710J/mol

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