Q.

The standard free energy of formation MgO  and CO at temperature 1000° C and 2000° below C (they refer to the reaction involving one mole of oxygen at one atmosphere pressure).

The free energy change to the reaction.

2Mg+O22MgOΔG1000C=941kJ/molΔG2000C=341kJ/mol

2C+O22CO ΔG1000C=439kJ/molΔG2000C=628kJ/mol

The following reaction is feasible at :

2MgO+2C2Mg+2CO

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a

Both (a) and (b)

b

None of the above

c

At 2000° C temperature

d

At 1000° C temperature

answer is B.

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Detailed Solution

The reaction is ,

2MgO+2C2Mg+CO

                                   ΔGReaction =ΔGCOΔGMgO

At 1000C,ΔG=439+941>0 (Non-spontaneous)

At 2000C,ΔG=628+341<0 (Spontaneous)

Thus, the reaction is feasible at 2000 degree celcius.

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The standard free energy of formation MgO  and CO at temperature 1000° C and 2000° below C (they refer to the reaction involving one mole of oxygen at one atmosphere pressure).The free energy change to the reaction.2Mg+O2→2MgOΔG1000∘C=−941kJ/molΔG2000∘C=−341kJ/mol2C+O2→2CO ΔG1000∘C=−439kJ/molΔG2000∘C=−628kJ/molThe following reaction is feasible at :2MgO+2C⟶2Mg+2CO