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Q.

The standard heat of formation values of SF6(g), S(g) and F(g) are: -1100, 275 and 80 kJ mol1 respectively. Then the average S - F bond energy  (in kJ mol1 ) in SF6 is ___ (Round off to nearest integer)

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answer is 309.

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Detailed Solution

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S(g) + 6F(g)SF6(g) ; ΔHf=1100 kJ mol1

S(s)S(g) ; ΔH = +275 kJ mol1

½ F2(g)F(g) ; ΔH = 80 kJ mol1

Therefore heat of formation = Bond energy of reaction - Bond energy of product 

1100 = [275 + 6×80][6×SF]

Thus bond energy of SF = 309 kJ mol1

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