Q.

The standard oxidation potential of Ni/Ni+2  electrode is 0.236V  if this combined with hydrogen electrode in acid solution. At what  pH of the solution the measured emf will be zero at  250C and 1 atm pressure  (assuming(Ni+2) =1M,        2.303RTF=0.059) (Round off to nearest integer)

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answer is 4.

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Detailed Solution

Ni+2H+Ni2++H2 0=0(0.236)0.0592log1[H+]2 pH=0.2360.059=4

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