Q.

The standard potentials (E0) for the half reactions are as 
ZnZn2++2e,E0=+0.76VFeFe2++2e,E0=+0.41V
the emf for the cell reaction Fe2++ZnZn2++Fe is 

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a

– 1.17 V

b

– 0.35 V

c

+ 1.17 V

d

+ 0.35 V

answer is B.

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Detailed Solution

Zn2++2 e-Zn; Eo= +0.76V FeFe2++2e- ; Eo = +0.41V 

Given are oxidation potentials.
Reduction potentials are equal and opposite. 
Fe forms cathode and Zn forms anode.

Ecello= Ereduction o+EOxidation o          = (-0.41)+(0.76)          =+ 0.35V  

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