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Q.

The standard potentials of Cu2+Cu and Cu+Cu are 0.337V and 0.521V respectively. The standard potential of Cu2+,Cu+Pt half cell is

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a

0.184 V

b

0.827 V

c

0.153 V

d

0.490 V

answer is C.

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Detailed Solution

Cu2++2eCu    ΔG1=2F(0.337V)Cu++eCu    ΔG2=F(0.521V)Cu2++eCu+    ΔG3=ΔG1ΔG2=F(0.674V0.521V)=F(0.153V)Hence ECu+Cu=0.153V

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