Q.

The standard reduction potential for Fe2+/Fe and Sn2+/Sn electrodes are -0.44 and -0.14 volt respectively. For the given cell reaction Fe2++SnFe+Sn2+, the standard EMF is 

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a

+0.58 V

b

-0.30 V

c

+0.30 V

d

-0.58 V

answer is D.

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Detailed Solution

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From the given Cell reaction Sn is acting as cathode and Fe is acting as anode 

Ecell=Ec-Ea=-0.44-(-0.14)=-0.3V

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The standard reduction potential for Fe2+/Fe and Sn2+/Sn electrodes are -0.44 and -0.14 volt respectively. For the given cell reaction Fe2++Sn→Fe+Sn2+, the standard EMF is