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Q.

The standard reduction potential of Cu2+ /Cu and Cu⁺ / Cu are 0.337 and 0.153V respectively, the standard electrode potential of Cu²⁺ / Cu⁺ half cell will be

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a

0.521V

b

0.490V

c

0.827V

d

0.184V

answer is C.

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Detailed Solution

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$\begin{array}{l} (1 E_{1}^{0} + 1 E_{2}^{0}) = 2 E_{3}^{0} \\ E_{1}^{0} + 0 .153 = 2 (0 .337) \\ E_{1}^{0} = 0 .521 V \end{array}$

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