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Q.

The standard reduction potentials for the two half-cell reactions are given below :  
Cd2+(aq)+2eCd(s);E0=0.40V; Ag+(aq)+eAg(s);E0=0.80V
The standard free energy change for the reaction
2Ag(aq)++Cd(s)2Ag(s)+Cd(aq)2+ is given by 
 

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a

-115.8 Kj  

b

231.6 kJ 

c

115.8 kJ

d

-231.6 kJ

answer is C.

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Detailed Solution

Ecell 0=EAgECd=0.8(0.4)=1.2V
ΔG0=nFE0=2×96500×1.2=231600J=231.6kJ

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The standard reduction potentials for the two half-cell reactions are given below :  Cd2+(aq)+2e−→Cd(s);E0=−0.40V; Ag+(aq)+e−→Ag(s);E0=0.80VThe standard free energy change for the reaction2Ag(aq)++Cd(s)→2Ag(s)+Cd(aq)2+ is given by