Q.

The stepwise formation of [Cu(NH3)4]2+ is given below.

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Detailed Solution

In, Cu2++NH3​⇌K1​​[Cu(NH3​)]2+


= [Cu(NH3​)]2++NH3​⇌K2​​[Cu(NH3​)2​]2+ 


= [Cu(NH3​)2​]2++NH3​⇌K3​​[Cu(NH3​)3​]2+ 


= [Cu(NH3​)3​]2++NH3​⇌K4​​[Cu(NH3​)4​]2+ 


Stability constants values are as follows

K1​,K2​,K3​ and K4​ are 104,1.58×103,5×102 and 102

Whereas, K=K1×K2×K3×K4; K=7.9×1011

K'= 1K  K' = 17.9 ×1011  = 1.26 ×10-12  = x is 1.26 

 

 

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