Q.

The strength of 11.2 volume solution of H2O2 is [Given that molar mass of H =1 g mol-1 and O = 16 g mol-1]

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a

1.7%

b

34%

c

13.6%

d

3.4%

answer is B.

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Detailed Solution

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11.2 volume strength of H2O2 indicates that 11.2 L of oxygen gas is produced from 1 liter of H2O2 solution. Decomposition reaction of H2O2 is:

2H2O22H2O+O2

Above reaction states that 2 moles or 68 g of hydrogen peroxide forms 22.4 L of oxygen gas. Mass of hydrogen peroxide required for the formation of 11.2 L of oxygen gas is:

22.4 L O2=68 g H2O211.2 L O2=11.2 L O2×68 g H2O222.4 L O2 =34 g H2O2
Total volume of solution is 1 L and the strength of H2O2 is 34 g/L.

Strength of 11.2 volume solution of H2O2 is calculated as:

1000 mL (or 1 L)=34 g H2O2100 mL=100 mL×34 g H2O21000 mL =3.4%

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