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Q.

The structure of a molecule of N(SiMe3)3 is :

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a

bent T-shaped with angle close to 89

b

pyramidal with angle close to 110

c

T-shaped with angle 90

d

trigonal planar with bond angle close to 120°

answer is D.

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Detailed Solution

When left outside in the open, N(SiMe3)3 feels waxy to the touch. The solid-state structures of these compounds have been determined by single-crystal X-ray diffraction studies.N(SiMe3)3 has a twisted core nitrogen atom that displays approximately trigonal planar coordination.
Due to back bonding, nitrogen hybridization is sp2.

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