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Q.

The substance undergoes first order decomposition. The decompostion follows two parallel first order reactions as :

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k1=1.26×104sec1 and k2=3.8×105sec1

The percentage distribution of B and C is :

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a

90%B and 10% C

b

76.83% B and 23.17% C

c

80% B and 20% C

answer is B.

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Detailed Solution

The ratio,

[B][C]=k1k2 %[B]=k1k1+k2×100

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The substance undergoes first order decomposition. The decompostion follows two parallel first order reactions as :k1=1.26×10−4sec−1 and k2=3.8×10−5sec−1. The percentage distribution of B and C is :