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Q.

The successive equilibrium constants for the stepwise dissociation of a tribasic acid are K1,K2 and  K3 respectively. The equilibrium constant for the overall dissociation

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a

K1+K2+K33

b

K1+K2+K3

c

K1×K2×K3

d

K1×K2×K33

answer is D.

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Detailed Solution

Tribasic acid = H3A

H3AH++H2A, Kc=K1 H2AH++HA2,  Kc=K2 HA2H++A3, Kc=K3

Net reaction: H3A3H++A3, Kc=K1×K2×K3

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