Q.

The sulphate of a metal M contains 9.87% of M. This sulphate is isomorphous with ZnSO47H2O. The atomic weight of M is 

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a

40.3

b

24.3 

c

11.3

d

36.3

answer is C.

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Detailed Solution

As the given sulphate is isomorphous with ZnSO47H2O its formula would be

MSO47H2Om is the atomic weight of M, Molecular weight of 

MSO47H2O=m+32+64+126=m+222

Hence % of M =mm+222×100=9.87 (given) or

100m=9.87m+222×9.87 or 90.13m=222×9.87 or m=222×9.8790.13=24.3

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