Q.

The sulphate of an element contains 42.2% element. The equivalent mass would be

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a

51.0

b

35.0

c

68.0

d

17.0

answer is B.

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Detailed Solution

Let X be the element then the formula would be : XSO4

Since the element is 42.2%, the SO4 would be :

100%-42.2%=57.8%

Molar mass of SO4 :

64+32=96  g/ mole 

This represents 57.8%

Mass of element is thus: 0.4220.578 × 96 = 70.09

Equivalent weight = molecular weight/valency factor.

Therefore the equivalent weight =70.09/2=35  ( valency factor for sulphates is 2).

Hence option B is the correct answer.

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