Q.

The sum of stereoisomers formed in the square planer complexes A, B & C in the following reaction sequence. (Ignore Tran’s effects)

[PtCl4]22Cl+2Py[A]Cl+NH3[B]Py+Br[C], Py- Pyridine

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answer is 7.

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Detailed Solution

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Complex A [Pt(Py)2Cl2] - 2 isomers
Complex B [Pt(Py)2(NH3)Cl] - 2 isomers
Complex C [Pt(Py)(NH3)ClBr] - 3 isomers

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