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Q.

The table shown below gives the bond dissociation energies Ediss  for single covalent bonds of carbon (C) atoms with element A, B, C and D. Which element has the smallest atoms.

BondEdiss (kJ/mol)
C-A240
C-B328
C-C276
C-D485

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a

A

b

B

c

C

d

D

answer is D.

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Detailed Solution

The bond length is inversely proportional to the bond energy. This means that a shorter length corresponds to a high dissociation energy, and vice-versa. In the given table, C-D has the highest bond dissociation energy, implying that C-D has the shortest bond length. As a result, the smallest atom is D.

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