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Q.

The temperature coefficient of a reaction is 2.5. If its rate constant at T1K is 2.5×103s1, the rate constant at T2K in s1 is T2>T1

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a

1.0×10–3

b

6.25×10–3

c

1.0×10–2

d

6.25×10–2

answer is B.

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Detailed Solution

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  • The temperature coefficient is the number of times the rate constant increases when the temperature is increased by 10oC.
  • It is given to us that T2 is higher than T1
  • Therefore, we can write that KT2KT1=2.5
  • Where, the rate constant at temperature T2 kelvin is denoted by KT2 and the rate constant at temperatureT1 kelvin is denoted by KT1.
  • KT22.5×10-3s-1=2.5 KT2=6.25×10-3 s-1
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