Q.

The tetrahedral crystal field splitting is only....... of the octahedral splitting.

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a

49

b

12

c

59

d

29

answer is C.

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Detailed Solution

Crystal Field Stabilization Energy (CFSE) is the additional stabilization gained by the splitting of the d-orbitals. The tetrahedral CFSE is expressed as Δt and octahedral CFSE is expressed as Δo.

In crystal field theory, it can be shown that the amount of splitting in a tetrahedral field is much smaller than in an octahedral field. In general,

Δt=49Δ0

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