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Q.

The thermal dissociation equilibrium of  CaCO3(s) is studied under different conditions CaCO3(s)CaO(s)+CO2(g) For this equilibrium, the correct statement(s) is (are)

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a

K is dependent on the pressure of CO2 at a given T

b

ΔH is independent of the catalyst, if any

c

ΔH is dependent on T

d

K is independent of the initial amount of CaCO3 

answer is A, B, D.

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Detailed Solution

CaCO3(s)CaO(s)+CO2|g|KP=PCO2atequilibrium  For a given reaction. Keq depends only on temperature.

Keq depends only on temperature. Enthalpy of reaction is independent of the catalyst. Catalyst generally changes activation energy.

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