Q.

The thermal dissociation of equilibrium of NaNO3(s)  is studied under different conditions.
  2NaNO3(s)2NaNO2(s)+O2(g)
For the equilibrium, the correct statement(s) is/are

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a

 Kc is dependent on the initial amount of  NaNO3.

b

At a particular temperature, the pressure of O2(g)  can have only one value.

c

ΔH  is independent of the catalyst, if any. 

d

ΔH  is independent of temperature.

answer is C, D.

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Detailed Solution

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ΔH of  a reaction depends on temperature and is given by Kirchoff’s equation.
 Kc=[O2]
Kp=pO2 which can have only one value at a particular temperature.
Catalyst does not change the energy of the reactant or product.

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