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Q.

The thermal stability of ${BaCO}_{3}, {CaCO}_{3}, {SrCO}_{3} and {MgCO}_{3}$ decreases in the order :

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a

${BaCO}_{3} > {SrCO}_{3} > {CaCO}_{3} > {MgCO}_{3}$

b

${MgCO}_{3} > {CaCO}_{3} > {SrCO}_{3} > {BaCO}_{3}$

c

${CaCO}_{3} > {SrCO}_{3} > {MgCO}_{3} > {BaCO}_{3}$

d

${BaCO}_{3} > {SrCO}_{3} > {MgCO}_{3} > {CaCO}_{3}$

answer is D.

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Detailed Solution

Thermal stability of ionic salts with polyatomic anions $\propto \frac{1}{M^{n +} (ϕ value)}$
${BaCO}_{3} > {SrCO}_{3} > {CaCO}_{3} > {MgCO}_{3}$

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