Q.

The three important oxidation states of phosphorous are

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a

– 3, + 3 and + 5

b

– 3, + 3 and – 5

c

– 3, + 4 and – 4

d

– 3, + 3 and + 4

answer is A.

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Detailed Solution

  • There are five valence electrons on P (3s2 3p3), where only three electrons of p-orbitals involve in bond formation due to inert pair effect. Hence, +3 oxidation state is one of the important oxidation states of phosphorus.
  • There are five valence electrons on P (3s2 3p3) where all valence electrons involve in bond formation. Hence, +5 oxidation state is also one of the important oxidation states of phosphorus.
  • There are five valence electrons on P (3s2 3p3) and required only three electrons to achieve a noble gas configuration. Hence, -3 oxidation state is also one of the important oxidation states of phosphorus.

Hence option D is correct.

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The three important oxidation states of phosphorous are