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Q.

The total possible co-ordination isomers for the following respectively are

Co(en)3] [Cr(C2O4)3

Cu(NH3)4 CuCl4

Ni(en)3 Co(NO2)6

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a

2,2,4

b

2,2,2

c

4,2,4

d

4,4,4

answer is D.

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Detailed Solution

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Co(en)3] [Cr(C2O4)3 , Co(C2O4) (en)2 , Cr(C2O4)3 (en)2CoC2O42(en),Cr(en)3CoC2O43 Total coordination isomers =4

[Cu(NH3)4] [CuCl4], [CuCl(NH3)3] [CuCl3(NH3)]  Total coordination isomers =2

[Ni(en)3] [Co(NO2)6], [Ni(NO2)2(en)2] [Co(NO2)4 (en)], [Co(NO2)2 (en)2] [Ni(NO2)4(en)][Co(en)3] [Ni(NO2)6]    Total No. of coordination isomers=4

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