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Q.

The total volume of 0.1 M KMnO4 solution that are needed to oxidize 100 mg each of ferrous oxalate and ferrous sulphate in a mixture in acidic medium is:

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a

1.096 mL

b

1.32 mL

c

5.48 mL

d

none of these

answer is C.

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Detailed Solution

m-eq. of KMnO4 =m-eq. of FeC2O4 + m-eq. of FeSO4
(0.1×5)×V=1001443+1001521;
V = 5.48 mL

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