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Q.

The transformation  H2Ol,10CH2Os,10C at 1atm pressure is accompanied with Δsys S=20.5 J K1.• Which of the following facts will hold good for the change in entropy of surrounding ΔsurS?

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a

Δsurr S<Δsys S

b

Δsurr S=0

c

Δsur S=ΔsysS

d

Δsurr S>Δsys S

answer is B.

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Detailed Solution

Since the transformation H2O1,10CH2Os,10C is irreversible or spontaneous, Δtotal S=Δsys S+Δsurr S>0.From this, it follows that Δsum S>Δsys S

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