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Q.

The  treatement  of an  Aqueous  solution of  3.74  gr of  Cu(NO3)2 with  excess  KI  results  in a  Brown  solution  along  with  the  formation  of a  precipitate .Passing  H2S Through  this  Brown  solution  gives   another  precipitate  x .The  number  of  Atoms  of  ‘x’  precipitate is  6.023×10y Then  y3  is (At. Wt of  Cu=63,S=32, N=14 , O=16 , H=1) 

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answer is 7.

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Detailed Solution

  Question Image
 Question Image    No. of  moles  of  Cu(NO3)2  = 3.74187=0.02

         2  moles of  Cu(NO3)2  gives 1 mole of  ‘S’ ppt
            0.02  moles of   Cu(NO3)2  gives 0.01mole of  ‘S’ ppt=  6.023×1021

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