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Q.

The treatment of ${CH}_{3} MgX$ with ${CH}_{3} C \equiv C - H$ produces

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a

${CH}_{4}$

b

${CH}_{3} CH = {CHCH}_{3}$

c

${CH}_{3} C \equiv {CCH}_{3}$

d

${CH}_{3} CH = {CH}_{2}$

answer is A.

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Detailed Solution

The acetylinic hydrogen on reacting with ${CH}_{3} MgX$ produces the alkane ${CH}_{4}$ .

${CH}_{3} C \equiv CH + {CH}_{3} MgX \to {CH}_{4} + {CH}_{3} C \equiv CMgX$

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The treatment of CH3MgX with CH3C≡C−H produces