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The triple point of ${CO}_{2}$ occurs at 5.1atm and $- 56^{\circ} C$ . Its critical temperature is $31^{\circ} C$ . Solid ${CO}_{2}$ is more dense than liquid ${CO}_{2}$ . Under which combination of pressure and temperature is liquid ${CO}_{2}$ stable at equilibrium?

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$10 atm$ and $- 25^{\circ} C$

$5.1 atm$ and $- 25^{\circ} C$

$5.1 atm$ and $- 100^{\circ} C$

$10 atm$ and $33^{\circ} C$

answer is A.

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Detailed Solution

At pressures less than 5.11177 atm, carbon dioxide has no liquid state. At 1 atm (0.101325 MPa), the gas deposits immediately to a solid below 194.6855(30) K and the solid sublimes directly to a gas above this temperature.

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