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The type of hybrid orbitals used by the central atom in perchlorate ion is

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sp²

sp³

dsp²

answer is A.

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Detailed Solution

ClO₄^- - Perchlorate ion

No of electron pairs = 1/2 [V + M - C + A]

V = No of valency electrons

M = No of monovalent atoms bonded to central atom

C = Total charge on cation

A = Total charge on anion

ClO₄^- :-

No of electron pairs = 1/2 [7 + 0 - 0 + 1]

No of electron pairs= 8/2 = 4 ⇒ sp³ - hybridisation

:. Cl in ClO₄^- uses sp³ hybrid orbitals. [OR]

ClO₄^-

Question Image

Each cross [x] indicates one electron of valency shell of chlorine

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