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Q.

The type of hybridization present on central atom is NiCN42-is 

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a

sp3

b

sp2

c

sp

d

dsp2

answer is D.

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Detailed Solution

Nickel has an atomic number of 28. Nickel’s electrical arrangement is Ni=[Ar]3d84s2.

There is a Ni2+ ion in N(CN)4-2 with the electrical configuration 3d84s0 in the valence shell.

All electrons are coupled up in the presence of strong CN- ligand. Complex has square planar geometry, where the vacant 3d, 3s, and two 4p orbitals undergo dsp2 hybridization to form bonds with CN- ligands. It’s a low-spin inner orbital complex

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