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Q.

The types of isomerism exhibited by [Co(NH3)5(NO2)](NO3)2 is

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a

Optical and ionization

b

Geometrical and linkage

c

Linkage and ionization

d

Co-ordination and hydrate

answer is B.

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Detailed Solution

[Co(NH3​)5​(NO2​)](NO3​)2​

The given compound can exhibit only linkage isomerism due to the presence of ambidentate ligand (−NO2​)

The complex in the left in the picture is [Co(NH3​)5​(NO2​)](NO2​)2​.

The complex in the right in the picture is [Co(NH3​)5​(ONO)](NO2​)2​.

So, the number of possible isomers is=2

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