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Q.

The value of γ=CpCv  for hydrogen, helium and another ideal diatomic gas X (whose molecules are not rigid but have an additional vibrational mode), are respectively equal to,

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a

53,75,75

b

53,75,97

c

75,53,97

d

75,53,75

answer is B.

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Detailed Solution

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Diatomic gases have 5 degrees of freedom, if vibrational mode is neglected. And if vibrational mode is also considered then degrees of freedom of diatomic gas molecules are 7.
For Hydrogen  γ=1+2f=1+25=75

For Helium γ=1+2f=1+23=53

For gas X (vibrational mode also considered) f = 7. 

γ=1+2f=1+27=97  So, 75,53,97

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