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Q.

The value of ΔfGfor formation of Cr2O3 is 540kJmol1 and that Al2O3 is 827kJmol1What is the value of ΔrG for the reaction? 
43Al(s)+23Cr2O3(s)23Al2O3(s)+43Cr(s)

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a

—574kJ mor-

b

—287kJ mo-1

c

+574kJ mot-

d

+287kJ mol -1

answer is B.

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Detailed Solution

The two equation are: 
43Al(s)+O2(g)23Al2O3(s),ΔfG=827kJmol1  ...(1) 43Cr(s)+O2(g)23Cr2O3(s),ΔfG=540kJmol1   ...(2)
Subtracting equation (ii) from equation (i) we have,  
43Al(s)+23Cr2O3(s) 23Al2O3(s)+43Cr(s), ΔrG=287kJmol1

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The value of ΔfG∘for formation of Cr2O3 is −540kJmol−1 and that Al2O3 is −827kJmol−1What is the value of ΔrG∘ for the reaction? 43Al(s)+23Cr2O3(s)→23Al2O3(s)+43Cr(s)