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Q.

The value of KC for each of the following equilibria respectively are 

 (i) 2NOCl(g)2NO(g)+Cl2(g) 

                                      Kp=1.8×10-2 at 500 K

 (ii) CaCO3(s)CaO(s)+CO2(g)

                                       Kp=167 at 1073 K 

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a

4.38×10-4, 1.89

b

4.3×10-5,2.89

c

4.38×10-4,289

d

4.3×10-5,1.89

answer is C.

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Detailed Solution

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 (i)  2NOCl(g)  2NO(g)+ Cl2(g)

KP=1.8×10-2  at 500 K

Δn = np-nr= 3-2 =1

KC=Kp(RT)Δn  =1.8×10-20.0821×500=4.38×10-4

 (ii) CaCO3(s)CaO(s)  CO2(g)

Kp=167  at  1073 K   Δn = np-nr =1

KC= Kp(RT)Δn

=1670.0821×1073=1.89

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