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Q.

The value of m for KCl and KNO3 are 149.86 and 154.96Ω-1Cm2 mol-1 Also λcl-  is 71.44 ohm-1cm2 mol-1 The value of λNO3- is

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a

76.54 ohm-1 cm2 mol-1

b

133.08 ohm-1 cm2 mol-1

c

37.7 ohm-1 cm2 mol-1

d

unpredictable

answer is A.

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Detailed Solution

λMKNO3=λM(K+)+λM(NO3-)=154.96

λMKCl=λM(K+)+λM(cl-)=149.86

λM(K+)+71.44=149.86

λM(K+)149.86-71.44

=78.42

78.42+λM(NO3-)=154.96

λM(NO3-)=154.96-78.42

=76.54

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