Q.

The value of n1+n2 and n22n12 for He+ ion in atomic spectrum are 4 and 8 respectively. The wavelength of emitted radiation when electrons jump from n2 to n1 is

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a

932RH

b

32RH9

c

329RH

d

9RH32

answer is B.

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Detailed Solution

 n22n12=8 ; n1+n2=4 n1+n2n1-n2=8 n1-n2=8/4=2

Hence n1=1, n2=3

ν-=1λ=RHZ21n12-1n22=RH22112-132=32RH9 λ=932RH

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