The values of a, for which the points A, B, C with position vectors 

 $2 \overline{\mathrm{i}} - \overline{\mathrm{j}} + \overline{\mathrm{k}}, \overline{\mathrm{i}} - 3 \overline{\mathrm{j}}- 5 \overline{\mathrm{k}}$ and$\mathrm{a}\overline{\mathrm{i}} - 3\overline{\mathrm{j}} + \overline{\mathrm{k}}$ respectively are the vertices of a right angled triangle with $\mathrm{C}=\frac{\mathrm{\pi }}{2}$ are