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Q.

The values of  E0 of some electrode reactions are given below
      I2  +  2e  2I         E0=0.54 voltsSn+4   +  2e  Sn2+        E0= 0.152 voltsCl2   +  2e   2Cl        E0= 1.36 voltsFe+3   +  e Fe2+        E0= 0.76 voltsCe+4   +  e     Ce3+    E0= 1.6 volts
Choose the correct statement(s) 
 

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a

Sn2+  will reduce  Fe3+ to Fe2+

b

Cl2  will be liberated from KCl  by passing  I2.

c

Ce4+  can oxidize  Fe2+

d

 Fe3+ oxidizes Ce+3

answer is B, C.

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Detailed Solution

Fe3++Ce3+Ce4++Fe2+ EO<0 I2+ClCl2+I EO<0

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