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Q.

The values of equivalent conductivity at infinite dilutions for NH4Cl, NaOH and NaCl are respectively 149.74, 248.1 and 126.4 ohm–1 cm2 eq–1. The value of λeq of NH4OH is ------------ohm-1 cm2 eq-1

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a

71.44

b

It cannot be calculated from the data given

c

371.44   

d

271.44

answer is B.

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Detailed Solution

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\lambda _{eq\left( {N{H_4}OH} \right)}^o = \lambda _{eq\left( {N{H_4}Cl} \right)}^o + \lambda _{eq\left( {NaOH} \right)}^o - \lambda _{eq\left( {NaCl} \right)}^o

 

 

= 149.74 + 248.1 - 126.4 = 271.44Sc{m^2}e{q^{ - 1}}
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