Q.

The values of equivalent conductivity at infinte dilutions for NH4Cl, NaOH and NaCl are respectively 149.74, 248.1 and 126.4 ohm–1 cm equi 1. The value of λ eq of NH4OH is  

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a

71.44

b

It cannot be calculated from the data given

c

271.44

d

371.44

answer is B.

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Detailed Solution

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According to Kohlrausch's law of equivalent conductivity, it could be stated:

NH4OHo=NH4Clo+NaOHo- NaClo                 = 149.74+248.1-126.4                  =271.44 ohm-1.cm2eq-1.

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