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Q.

The van der Waals equation for one mol of CO2 gas at low pressure will be

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a

P+aV2V=RT

b

P(Vb)=RTaV2

c

P=RTVb

d

P=RTVbaV2

answer is A.

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Detailed Solution

P+aV2(Vb)=RT

At low pressure, volume is high and b may be ignored.
So van der Waals equation becomes

P+aV2V=RT

Hence, the answer is (1). 

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