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Q.

The vapour pressure of an aqueous solution is found to be 750 torr at certain temperature ‘T’, If ‘T’ is the temperature at which pure water boils under atmospheric pressure and same solution show elevation in boiling point  ΔTb=1.04K, find the atmospheric pressure in torr (Kb=0.52Kkgmol1 )

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answer is 777.

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Detailed Solution

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ΔTb=Kbm

m=(ΔTb0.52)=1.040.52=2  mole/kg

also P°PsPs=nBnA=m.MA

P°Ps1=2(18)×103

P°Ps=1+36×103=1.036

P°=777  torr

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