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Q.

The vapour pressure of water at 20 °C is 17.5 mmHg. If 18 g of glucose (C6H12O6 ) is added to 178.2 g of water at 20 °C, the vapour of the resulting solution will be

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a

15.750 mmHg

b

17.675 mmHg

c

16.500 mmHg

d

17.325 mmHg

answer is A.

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Detailed Solution

Amount of glucose, n2=m2M2=18g180gmol1=0.1mol

Amount of water, n1=m1M1=178.218gmol1=9.9mol

Mole fraction of water, x1=n1n1+n2=9.9g(9.9+0.1)mol=0.99

Vapour pressure of solution, p=x1p1=(0.99)(17.5mmHg)=17.325mmHg.

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