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Q.

The volume (in ml) of 0.1M $A g N O_{3}$ required to quantitatively precipitate chloride ions in 30ml of 0.01M solution of $[C r {(H_{2} O)}_{5} C l] C l_{2}$ as $A g C l$ is?

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answer is 6.

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Detailed Solution

$2 A g N O_{3} + [C r {(H_{2} O)}_{5} C l] C l_{2} \overset{}{\to} 2 A g C l ↓ (w h i t e p p t)$

$\frac{M_{1} V_{1}}{n_{1}} = \frac{M_{2} V_{2}}{n_{2}}$

$\frac{0.1 \times V}{2} = \frac{30 \times 0.01}{1}$

$∴ V = 6 m l$

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The volume (in ml) of 0.1M AgNO3 required to quantitatively precipitate chloride ions in 30ml of 0.01M solution of [Cr(H2O)5Cl]Cl2 as AgCl is?