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Q.

The volume (in mL) of 0.1 M AgNO3 required for complete precipitation of chloride ions present in 30 mL of 0.01 M solution of [Cr(H2O)5Cl]Cl2, as silver chloride is close to

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a

2

b

6

c

9

d

3

answer is B.

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Detailed Solution

Number of ionisable Cl–[Cr(H2O)5Cl] is 2
∴ Millimoles of Cr– = 30 x 0.01 x 2=0.6
Millimoles of required = 0.6
∴0.6=0.1V;V=6ml

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