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Q.

The volume of gases H2,CH4,CO2&NH3 adsorbed by 1g of activated charcoal at 298 K & 1 atm pressure are in the order

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a

CH4>CO2>NH3>H2

b

NH3>CO2>CH4>H2

c

H2>CH4>CO2>NH3

d

CO2>NH3>CH4>H2

answer is D.

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Detailed Solution

The amount of gas adsorbed by a solid depends on the nature of gas. In general, more easily liquefiable gases (i.e., higher critical temperature) are readily adsorbed as vander Waals forces are stronger near the critical temperatures.

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Thus, 1g of activated charcoal adsorbs 380 mL of sulphur dioxide (critical temp. 157°C), 16 mL of methane (critical temp. -83°C) and 4.5 mL of hydrogen (critical temp. -240°C)

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