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Q.

The volume of 0.1 M oxalic acid that can be completely oxidized by 20 ml of 0.025 M KMnO4 solution is-

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a

2.5 ml

b

25 ml

c

12.5 ml

d

5 ml

answer is C.

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Detailed Solution

H2C2O4CO2RA ;   KMnO4Mn+2OA nf = 2                        nf = 5 meqH2C2O4   =   meqKMnO4 M × V × nf  = M × V × nf 0.1 × V × 2 = 0.025 × 20 × 5 V = 12.5 ml

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