Q.

The volume strength of H2O2 solution if 50ml of H2O2 solution is diluted with 50ml of H2O. 20ml.
of this diluted solution required 40mL of M/60 K2Cr2O7 solution in presence of H2SO4 for complete
volume is ———

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a

22.4V

b

2.24V

c

1.12V

d

11.2V

answer is D.

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Detailed Solution

m eq of H2O2 = m eq of K2Cr2O7 
M. nf. V = M. nf. V 
N V = N V ; N × 20 = 1/6 × 6 ; N = 0.2 N 
The normality of 50ml of H2O2 solution is twice than 20ml of solution since it diluted for double volume. 
N1.V1 = N2.V2 ; 0.2 × 100 = N2.50ml 
N2 = 0.4N 
Volume strength of H2O2 
= N × 5.6. 6 × 0.4 = 2.24 V

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The volume strength of H2O2 solution if 50ml of H2O2 solution is diluted with 50ml of H2O. 20ml.of this diluted solution required 40mL of M/60 K2Cr2O7 solution in presence of H2SO4 for completevolume is ———